Angelina Jolie and Brad Pitt
This power couple of Hollywood are not only known for their drop-dead gorgeous looks, their humanitarian work, or money, but also for their beautiful twins who are one-sixth of a confident brood! The couple that hit it off during the filming of Mr and Mrs Smith (2005), announced the arrival of their twins Vivienne and Knox in 2008. The twins are fifth and sixth in-line after the couple's three adopted children. Pitt and Jolie tied the knot last year in an elegant and very private ceremony.